By John Sawyer, Department of Agronomy
If you are considering fall application of anhydrous ammonia to corn fields (the only nitrogen fertilizer recommended for fall application), remember to wait until soil temperatures cool to 50° F and continue to trend colder. The same guidance applies to manure with high ammonium N content, like liquid swine manure.
Why is waiting important?
The form of nitrogen that can potentially be lost from soils due to wet conditions is nitrate (NO3-) (Figure 1). The form applied as anhydrous ammonia is NH3, which converts to ammonium (NH4+) in water. Because ammonium is a positively charged ion, it is attracted by electrostatic forces to the negatively charged soil. Ammonium is not leached or lost by denitrification (conversion to nitrogen gas). Therefore, it will stay in soil even if the soil becomes excessively wet. Nitrate, which is produced by soil microbes from ammonium in a process called nitrification, is a negatively charged ion, is repelled by the negatively charged soil, and is leachable and subject to denitrification.
Figure 1. Simplified soil nitrogen cycle.
Since nitrification is a microbial-mediated process, the rate is influenced by several factors that affect biological activity, such as ammonia in soil water (inhibits nitrification), temperature, soil aeration (only occurs in aerobic soils), soil pH – range from 4.5 to 10.0 (optimum at pH 8.5), and soil moisture (highest at field capacity); but the largest influence is soil temperature. For that reason, a way to slow conversion of ammonium to nitrate is to have cold soil temperatures (example of soil temperature effect on nitrification shown in Figure 2). The optimum temperature for nitrification is around 90° F. Below 50° F the rate slows rapidly, but nitrification continues until 32° F. Soil temperature cannot be controlled, but because soils cool in the late fall, then nitrification of late-fall applications will be reduced. The later one waits to apply the better –soils with colder temperatures mean less nitrification and a greater probability that soil temperature will not rebound to warm levels.
Figure 2. Effect of soil temperature on nitrate formation. Adapted from Frederick, L.R. and F.E. Broadbent. 1966. Biological interactions. p. 198-212. In M.H. McVicker et al. (ed) Agricultural anhydrous ammonia technology and use. ASA, Madison, WI.
Nitrification inhibitors slow the conversion of ammonium to nitrate. If more ammonium remains in soil during wet springtime periods, then less nitrate will be present and subject to loss. Nitrification inhibitors are not foolproof. They temporarily slow, but do not stop nitrification and formation of nitrate. They degrade in soil, which lessens effectiveness over time. Warm soils that speed nitrification also speed inhibitor breakdown, which means lower effectiveness and faster nitrification reestablishment. Also, nitrification inhibitor impact on N loss is solely dependent on substantially more ammonium being present during excessively wet periods (typically occur in the springtime). If wet soils occur after the inhibitor looses its ability to effectively enhance ammonium remaining, then it will have no real impact.
Waiting for cold soils and/or using a nitrification inhibitor does not guarantee that fall-applied N will be a completely successful practice. Late fall may be warm, or warm and wet conditions may occur the next spring (a time period with historically high potential for wet soils and nitrate loss is May - June). However, if one decides to make applications in the fall, then waiting until soils are cold is better than applying early.
Where to Find Soil Temperature Information
Soil temperatures can be found at several websites. One that gives the 3-day, 4-inch depth soil temperature estimates for each Iowa county is https://mesonet.agron.iastate.edu/agclimate/display.php?prod=2. The site can also be accessed through the Agronomy Extension Soil Fertility website at www.agronext.iastate.edu/soilfertility, either from the weather page or nitrogen topic page. You can find the average daily soil temperatures from yesterday, two days ago, and three days ago and you can get the 6-10 day weather forecast. The 4-inch soil temperatures are estimated for each county based on interpolation of observed soil temperatures at multiple locations. The estimates are for soil temperatures on level, bare soil.
Four-inch soil temperatures are available from the Iowa Environmental Mesonet (IEM) websites for the previous day average and for the high/low range.
Remember, the decision to begin fall N application is not the first day that temperatures reach 50° F, rather when the trend is for sustained soil temperatures below 50° F and continued cooling. The dates when soils cool below 50° F vary considerably, from late October to late November. Therefore, watch for temporary cold spells, especially early in the fall. Also observe the 6-10 day weather forecast, where a forecast for above average temperatures may signal soil warming.
John Sawyer is a professor of agronomy with research and extension responsibilities in soil fertility and nutrient management. He can be reached at firstname.lastname@example.org or 515-294-7078.
Links to this article are strongly encouraged, and this article may be republished without further permission if published as written and if credit is given to the author, Integrated Crop Management News, and Iowa State University Extension and Outreach. If this article is to be used in any other manner, permission from the author is required. This article was originally published on October 13, 2014. The information contained within may not be the most current and accurate depending on when it is accessed.